Finding Extraterrestrial Organics is Old News; Let's Look for Evidence of Life

There's a new mass spec study[1] of crystals from two meteorites, one of which in turn has material originating from two separate parent bodies. The objects were about 4.5 billion years old, i.e. dating to the birth of the solar system, and showed evidence of organics resulting from aqeous reactions. Some findings of interest: "...signatures of low-mass C5 to C10 hydrocarbons at around 70 to 200 atomic mass units." Not much benzene, suggesting that any aromatic rings are locked up in larger structures. We're finding organics everywhere we look it seems, including Ceres, and that includes even amino acids and nucleobases. Given how quickly after the Earth formed we started seeing evidence of self-replicating molecules (at least the ancestors of cells, if not cells themselves), this means that life originated quickly on Earth, and therefore was a highly probable event.

It's also relevant that polyaromatic hydrocarbons (PAHs - for instance, tar, graphite, anthracene in coal, and fullerenes) have been found in nebulas, as well as in Titan's atmosphere. Not only are they thought to be quite common in the universe, but possibly crucial to the origin of life (see PAH World Hypothesis.) PAH's are predicted to make up a large portion of the carbon at the surface of carbon planets. While carbon planet systems (unlike our own silicate system) were theorized only recently, it turns out that the Hypatia Stone, a bizarre meteorite found in the Egyptian desert, is loaded with PAHs and originated from outside our solar system - possibly as impact debris from just such a planet.[2] (It's becoming increasingly clear that objects from outside the solar system enter it frequently. First Wild-2 (which had amino acids in it), then Oamuamua, and now Hypatia. We've found these things on the Earth's surface without looking that hard for them! Given these observations, we should expect that interstellar mixing on relatively short geologic time scales is the rule.

This suggests several things and begs several questions.

- If a pile of complex molecules were delivered to Earth - say, a bunch of RNA that survived intact inside an impactor - that pushes back the question of the origin of life, but it also suggests it's very likely elsewhere.

- Have we looked for polymerized RNA or amino acids? Mass spec can detect and distinguish small fragments.[3]

- You might ask, why RNA? Why assume any similarity to Earth biochemistry? This raises the larger question of, if there is active extraterrestrial biochemistry in asteroids, how could we detect it? This is the question asked about desert varnish (which has been speculated as evidence of a shadow biosphere of non-DNA based life operating here on Earth under our noses.) If we did find alien biochemistry, how would we know what we were looking at, against the background of organics that we already know is there? While we haven't seen anything that obviously screams "alien biochemistry", that's the point - HOW does something look if it screams "alien biochemistry"? Are there general principles of such systems? You can't just look for macromolecules - if those are composed of the some monomers, they won't necessarily carry information (e.g. aliens trying to figure out our biochemistry from sequencing the fatty acids in our membrane phospholipids will not learn very much.) So it has to be a macromolecule with a limited number of discrete subunits. So far our samples have been limited t one biosphere. If we ever get enough complex organics from a sample return mission to be able to afford to destroy some of it in aqueous chemistry experiences, that will be a boon to astrobiology.

- If there is such a thing as a simple space-borne organism - or even the remnants of aberrant von Neumann probes that have "gone to seed" after eons-long selection for fecundity over their exploration functions - it would make sense to be adapted to low gravity bodies that are cheapest to move back and forth between. If Earth's biosphere is just overgrown von Neumann probes, that might just be because we're a dead end at the bottom of a gravity well.

Previous post on alien evolution, First Interstellar Asteroid? It's Interstellar, But Not the First We've Seen


REFERENCES

[1] Queenie H. S. Chan, Michael E. Zolensky, Yoko Kebukawa, Marc Fries, Motoo Ito, Andrew Steele, Zia Rahman, Aiko Nakato, A. L. David Kilcoyne, Hiroki Suga, Yoshio Takahashi, Yasuo Takeichi and Kazuhiko Mase. Organic matter in extraterrestrial water-bearing salt crystals. Science Advances 10 Jan 2018: Vol. 4, no. 1, eaao3521. DOI: 10.1126/sciadv.aao3521

[2] Georgy A.Belyanin, Jan D.Kramers, Marco A.G.Andreoli, Francesco Greco, Arnold Gucsik, Tebogo V. Makhubela, Wojciec, J.Przybylowicz, Michael Wiedenbeck. Petrography of the carbonaceous, diamond-bearing stone “Hypatia” from southwest Egypt: A contribution to the debate on its origin. Geochimica et Cosmochimica Acta, Volume 223, 15 February 2018, Pages 462-492.

[3] Zhaojing Meng and Patrick A. Limbach. Mass Spectrometry of RNA: Linking the Genome to the Proteome. Brief Funct Genomic Proteomic. 2006 Mar; 5(1): 87–95.